Top 5 TV Characters.
 

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1.Gabrielle Solis (Desperate Housewives)
2.Glenn Rhee (The Walking Dead)
3.Annalise Keating (How To Get Away With Murder)
4.Emily Thorne (Revenge)
5.Spencer Hastings (Pretty Little Liars)

1. Chloe O'Brien
2. Martha Logan
3. Nina Myers
4. David Palmer
5. Charles Logan

(Just felt like ranking 24 characters tbh)

1. Benjamin Linus (Lost)
2. Carol Peletier (The Walking Dead)
3. The Machine (Person of Interest)
4. Varys (Game of Thrones)
5. John Greer (Person of Interest)

1. Edie Britt
2. Jules Cobb
3. Melinda Gordon
4. Max Black
5. Stef Adams

1. Valerie Cherish (The Comeback)
2. Martha Logan (24)
3. Willow Rosenberg (Buffy)
4. Chloe O'Brien (24)
5. Charlie Pace (Lost)

(Decided to do a proper one)

Frasier Crane, Walter White, David Brent, Sarah Lund & Roger Smith

Alf Garnett (Till death us do part)
Rigsby (Rising Damp)
Albert Steptoe (Steptoe and Son)
Victor Meldrew (One foot in the grave)
Captain Mainwaring (Dads's Army)

Top of my head atm

Silas Blissit (Hollyoaks)
Homer J Simpson (The Simpsons)
Gohan (Dragon Ball Z)
Castiel (Supernatural)
Britta (Community)

1. Glenn Rhee (TWD)
2. Leslie Knope (Parks & Recreation)
3. Michael Scott (The Office US)
4. Cristina Yang (Grey's Anatomy)
5. Walter White (Breaking Bad)

I forgot about Karen Walker, I'd like to add her to my list

1. Buffy Summers (Buffy the Vampire Slayer)
2. Brooke Davis (One Tree Hill)
3. Carol Peletier (The Walking Dead)
4. Samantha Jones (Sex and the City)
5. Beth Greene (The Walking Dead)

Cosima Niehaus (Orphan Black)
Dany Targaryen (Game of Thrones)
Thomas Shelby (Peaky Blinders)
Pam Beesley (The Office)
Gemma Foster (Doctor Foster)

In no particular order... (A top 5 is near impossible)

Rick Grimes - The Walking Dead
Michael Scott - The Office US
Dwight Schrute - The Office US
James Cook - Skins
Effy Stonem - Skins