[Deus Ex Machina]

I was at a mates house yesterday while he was working, and I'm watching MTV and there's a really good song on it, but for boring reasons that I won't explain I missed the details of what it was called and who it was by.
So, now I'm looking for someone that has seen it.

It featured a bloke with his lip pierced who played a guitar and sang, and a woman with black angel wings who also sang.
They wandered around in some kind of wasteland with burnt out cars and stuff until they found the rest of the band, then they started rockin'.

Anyone?